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Uncertainty Analysis for
Hydrocarbon Measurement

This article has been prepared to give some guidance on how uncertainty estimation can be carried out, how to overcome some of the statistical anomalies found in oil industry practice, and how to prepare for a consistent expression of uncertainty, that is compatible with international metrology practice, says R Paton.

Introduction
Within the oil industry, measurement has always been of prime importance in the transfer of product both onshore and offshore. When calculating duty payable or allocation, the accuracy in measuring the quantity of oil is vital. It can be argued that when trading oil, consistency and agreement in measurement between buyer and seller is more important than accuracy (or even the correct value of the quantity!).  However, to achieve consistency, you have to measure accurately, and to judge if you have consistency you have to know the uncertainty.

Throughout the production and distribution chain the accuracy of the measurements has always been important.  The term accuracy is easily understood and comes into all specifications of measurements across all fields of metrology. It is, by definition, a qualitative term.  Accuracy will usually have a number attached but will not define the level of confidence of the measurement. In recent years the oil industry has followed the general trend in metrology and recognised that ‘accuracy’ is inadequate to provide the information needed for transactions.

An estimate of uncertainty of measurement must include (explicitly or implicitly) the confidence in the estimate. Increasingly this is demanded as a measure to accompany any result. As the need to express uncertainty increases, it has become clear that the methods and traceability chains used in the oil industry do not easily adapt to the methods of estimating uncertainty provided by the statistically based standards in the scientific and pure metrology fields. To retain consistency it is vital that estimation of uncertainty must be carried out in a statistically sound and auditable manner, but in a way that the engineers in the industry can relate to. In many cases, uncertainty estimation is an art rather than a science and it would be rare that two independent engineers would derive the same value. This is an untenable situation in the oil industry where, on transactions, agreement can be more important than accuracy. Unfortunately, until many more uncertainty calculations are carried out and input figures agreed, no standardisation would be possible.

This article has been prepared to give some guidance on how uncertainty estimation can be carried out, how to overcome some of the statistical anomalies found in oil industry practice, and how to prepare for a consistent expression of uncertainty, that is compatible with international metrology practice. By following the principles set out in this article, it will also be possible to set the expected uncertainty for transactions where all the input measurements are within specified limits. The actual uncertainty may be better but only individual analysis would determine that.

Historically, the oil industry has had to meet the practical needs of measurement in arduous conditions. As a result, uncertainty calculations using a common methodology had not been of high priority. Traditionally, measurement of ‘accuracy’ was defined for secondary measurements such as temperature and much emphasis had been placed on the repeatability of measurements based on a very small sample of results. From this an overall view of the resultant accuracy was assumed.

 Uncertainty estimation has rarely been carried out thoroughly and, using a pragmatic examination of results and agreement between parties, accuracy has been defined by agreement. Similarly many of the methods used to collect data during calibrations, appear, at first sight, to make rigorous uncertainty estimation very difficult. Commercial and operational requirements generally prevent the collection of data in the quantity expected from any scientific based measurement.

The need to estimate uncertainty has become more important in recent years to improve the confidence in mass balance across systems and reliably fine tune ever faster contract specifications and regulatory requirements.  It is vital that these uncertainty estimates are carried out in a consistent manner and are understood by all parties.  All estimates of uncertainty must carry a confidence limit, but more importantly they must have the confidence of operators, contract staff, partners and regulators.

To comply with measurement standards from ISO etc, uncertainty should be included in the standard and this will carry over into regulation and contracts.  Acceptance limits (criteria), accuracy expectations and repeatability criteria will continue to feature strongly in practical standards and procedures. Such criteria are compliant with good practical metrology and can be used as an input to the definition of an uncertainty.

The international standards bodies recognised that a statistically sound methodology was required to service the need for uncertainty estimation in metrology and hence produced the Guide to Uncertainty of Measurement (GUM).  The introduction of the guide was met with some resistance from the industry but overwhelming enthusiasm by scientific based metrologists and adopted by the standards bodies. Within ISO and IEC all new standards are encouraged to include uncertainty criteria and it is now up to industry to make these follow the guide.

What is obvious is that the GUM does not relate easily to the history and realities of practical industries. The GUM expresses uncertainty in statistical terms different to the established methods familiar to most measurement engineers. It is heavily scientifically and statistically based. The GUM is however a guide, not a standard! It is now up to individual industries to follow the methods and apply them to their own needs.

Gum: The Principles

Traditionally, uncertainty was derived by combining all estimates of the magnitude of individual errors in a measurement. This provides an estimate of systematic error in the final quantity. To this systematic error, the estimate of random uncertainty is added by taking a statistical result from multiple measurements to estimate the probability distribution of the result, hence providing a confidence band.

The principles outlined in the GUM are the same but the approach and terminology is different.

The fundamental concept of the GUM is to assume all uncertainties are equivalent to the standard deviation of the results from many repeated tests. By assuming this, all uncertainties can be assigned a probability function and hence the final uncertainty fully recognises the potential distribution of results and gives a much better confidence expression through a coverage factor or confidence limit.  This concept is sound, but the application to industry where most uncertainties are not derived from (apparent) knowledge of large numbers of tests requires some consideration.

A number of terms are used in this approach:

  • Standard Uncertainty: Standard uncertainty is the uncertainty of the result of measurements expressed as a standard deviation. All uncertainties are initially estimated as standard uncertainties. In deriving standard uncertainty, two types of uncertainty (type A and type B) are recognised.
  • Type A Uncertainties: Type A evaluations of uncertainty are those using statistical methods, specifically, those that use the spread of a number of measurements.Any measurement can be repeated a number of times and the statistical distribution found, analysed and the standard deviation and probability limits defined.  This is equivalent to the traditional random uncertainty but has been renamed in the GUM as a type A uncertainty.
  • Type B Uncertainties: Type B evaluation of uncertainty is one carried out by means other than the statistical analysis of a series of observations.It is recognised that in many cases it is impractical or impossible to gather enough data in the experiment to derive a representative statistical estimate from repeated measurements. This situation leads to the derivation of a type B uncertainty. Type B uncertainties are in some ways equivalent to the traditional systematic error. To achieve an estimate of standard uncertainty, type B uncertainties must be assessed not only on their magnitude, but also on the estimated probability distribution encompassed within the estimate. Within the GUM type B uncertainties are first estimated in magnitude, and then reduced to an equivalent standard uncertainty based on an assumed probability distribution. This is achieved by the application of a divisor to reduce the spread of uncertainty to standard uncertainty. 
  • Expanded Uncertainty and Coverage Factor: Expanded uncertainty is computed by combining all standard uncertainties, both type A and type B, and multiplying by a coverage factor chosen to express the results encompassed by a large fraction of the probable values reasonably attributed to the measurement. Generally, these confidence limits are accepted as being at 95% confidence levels.  As is explained in the GUM, a coverage factor is a better parameter to be used. This is the factor by which the standard uncertainty is multiplied to give the expanded uncertainty.
    If a normal distribution is assumed and a large number of results are assumed, k=2 approximates to a confidence of 95% (actually 95.45%) and k=3 is applied to approximate to a 99% confidence.
    Expanded uncertainty is therefore the final expression of an uncertainty analysis.  This is expressed formally as the measurement value with an expanded uncertainty and a coverage factor..

...contd.

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